Study of the kinetic regularities of the reaction of methane carbonate conversion

In this work, the reaction of carbonate conversion of methane was prepared on the basis of the "Sol-gel" technology (Ni₂O₃)x*(Co₂O₃)y*(Zro₂)z*(B₂O₃)κ: Al₂O₃ and (Ni₂O₃)x*(Co₂O₃)y*(Zro₂)z*(B₂O₃)k*:Al₂O₃ was studied in catalysts. As a result of studying the effect of temperature and other factors on the yield of reaction products in the presence of generated catalysts, the following optimal reaction conditions were determined: CH₄:CO₂ = 1:1; P = 0,1 MIIa; V0 = 1000 coam⁻¹; T=750°. The most active are Rh and Ru catalysts, intermediate activity is occupied by Ni and Ir, and the least active are Pt and Pd [2]. Co and Fe catalysts are also active in this process but are prone to oxidation [8]. In view of the high cost of catalysts based on Rh and Ru, steam reforming of methane is carried out on a Ni catalyst at a temperature of 850–1000°, a pressure of 1.5–3 MPa, and a methane flow rate of 1000 h⁻¹.