Asian Journal of Research in Chemistry
  • Year: 2017
  • Volume: 10
  • Issue: 4

Rapid determination of barium ions in water using ion selective electrode

Chemistry Research Laboratory, Department of Chemistry, B. N. Bandodkar College of Science, Chendani Bunder Road, Thane-400 601, Maharashtra (India).

*Corresponding Author E-mail: anitagoswami@yahoo.com

Online published on 17 October, 2017.

Abstract

Barium, an alkaline earth metal have been determined by numerous sophisticated analytical tools that are quite expensive and often involve sample pre-treatment. Present research manuscript is focused on a novel method for the determination of barium ions in water samples by employing a graphite electrode coated with barium selective membrane. The developed electrode with membrane composition of 33.0% polyvinyl chloride, 57.0% ortho nitro phenyl octyl ether, 6.0% sodium tetraphenyl borate, 2.0% multiwalled nanotube and 2.0% ionophore dibenzo 24 crown 8 was used and the results obtained were compared by ICP-AES method.

Keywords

Potentiometry, EMF, graphite electrode, barium ion, quantitative analysis