Bulletin of Pure & Applied Sciences- Chemistry
  • Year: 2012
  • Volume: 31c
  • Issue: 1

Apparent molar volumes and viscosity studies of amino acids in aqueous tertiary butyl alcohol at 303.15 K

  • Author:
  • S. Nagaraj1,, M.C.S. Subha1, C. Nagamani1, K. Chowdoji Rao2
  • Total Page Count: 18
  • Page Number: 1 to 18

1Department of Chemistry, S.K. University, Anantapur - 515003, Andhra Pradesh, India

2Department of Polymer Science and Technology, S.K. University, Anantapur - 515003, Andhra Pradesh, India

*Author to whom correspondence to be sent email: nagarajs.bc@gmail.com

Online published on 11 January, 2013.

Abstract

Densities and viscosities of Glycine, DL-Alanine, L-Valine and L-Arginine HCI have been measured in water + Tertiary butyl alcohol (TBA) mixtures ranging from pure water to 60% TBA by mass at 303.15 K. From the densities, apparent molar volumes and limiting apparent molar volumes of the four amino adds in the mixtures have been calculated. From the viscosity values, Falken hagen constant A and Jones-Dole constant B were calculated. These values were interpreted in terms of structure-breaking or structure making effects of these amino acids in the water + TBA mixtures.

Keywords

Apparent molar volume, Density, Viscosity, Amino acids, Tertiary butyl alcohol