*Corresponding Author K.N. Rajasekharan,
We wish to report the synthesis of 5-anilino-3-(3, 5-dimethylpyrazol-1-yl)-1, 2, 4-thiadiazoles by a solid state, mechanochemical oxidative cyclization of 3, 5-dimethyl-1-[N-(N'-arylthiocarbamoyl) amidino] pyrazoles, which in turn have also been accessed through a solvent free, green technique.
1, 2, 4-thiadiazole, mechanochemistry, hetarylthiocarbamoylamidine, oxidative cyclization, NMR analysis