Bulletin of Pure & Applied Sciences- Chemistry
  • Year: 2018
  • Volume: 37c
  • Issue: 1

Sensitized luminescence from novel pyrazolone based â-diketonate complexes of Eu3+

1P.G. & Research Department of Chemistry, Sree Narayana College, Kollam, 691001

*Corresponding Author D.B. Ambili Raj, P.G. & Research Department of Chemistry, Sree Narayana College, Kollam, 691001, E-mail: ambilrajdb@gmail.com

Online published on 28 February, 2018.

Abstract

New pyrazolone based fluorinated ligand, 3-methyl 4-(2, 2, 3, 3, 3-penta fluoro-1-hydroxypropylidene)-1-phenyl-1H-pyrazol-5(4H)-one has been synthesized and well characterized. Europium-containing complexes were synthesized by adduct formation between 3-methyl 4-(2, 2, 3, 3, 3-penta fluoro-1-hydroxypropylidene)-1-phenyl-1H-pyrazol-5(4H)-one and europium (III) complex and a bidentate neutral donor 1, 10-phenanthroline (phen). The emission spectra of the complexes display characteristic sharp peaks in the 575–700 nm region associated with the 5D0 _7FJ (J = 0–4) transitions of the Eu3+ ion.

Keywords

Lanthanide complex, PL properties, pyrazolone, fluorinated ligand, Eu3+