Bulletin of Pure & Applied Sciences- Chemistry
  • Year: 2018
  • Volume: 37c
  • Issue: 1

Spectral & biological characteristics of a novel Uranyl Proton transfer salt

1Dept. of Chemistry, Mannaniya College of Arts & Science, Pangode, Trivandrum

2Dept. of Chemistry, S.N College, Chempazhanthi, Trivandrum.

*Correspondizng Author Shiji Fazil, Dept. of Chemistry, Mannaniya College of arts & science, Pangode, Trivandrum, E-mail: shijifazil@gmail.com

Online published on 28 February, 2018.

Abstract

The reaction of UO2(NO3)2.6H2O with the proton transfer compound obtained from 2, 2'-dithiobis(benzoic acid) and 4-aminoantipyrine, (HAAP+. HTBA-), led to the formation of a novel complex of the formulae [(HAAP)2UO2(HTBA)2(NO3)2]. This complex was characterized using IR, elemental, NMR and magnetic measurement along with the single crystal X-ray study of the ion pair. The anion is a six coordinated complex with an octahedral geometry around the UO2(II) atom. UO2(II) complex and (HAAP+. HTBA-) were screened for antibacterial properties and have exhibited potential activity.

Keywords

4-aminoantipyrine, Uranyl, 2, 2'-dithiobis(benzoic acid), XRD