Bulletin of Pure & Applied Sciences- Chemistry
  • Year: 2018
  • Volume: 37c
  • Issue: 2

Excess Molar Enthalpies of Acetylene Tetrachloride with Furan, Methylfuran, Tetrahydrofuran and 1, 4-dioxane at the Temperature 308.15K

Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh, 244001, India

*Corresponding Author: Atri D. Tripathi, Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh, 244001, India, E-mail: atri34tmu@gmail.com

Online published on 21 August, 2018.

Abstract

The excess molar enthalpies HE of mixtures of acetylene tetrachloride with furan or methylfuran or tetrahydrofuran or 1, 4-dioxane have been measured over the entire composition range at the temperature Ts 308.15 K. The HE values are negative for all the mixtures over the whole composition range. The values for ndonor compounds increase in the order furan < methylfuran < 1, 4-dioxane< tetrahydrofuran. The HE values have been used to calculate the excess partial molar enthalpies of the respective components.

Keywords

Microcalorimeter, enthalpy of mixing, acetylene tetrachloride, tetrahydrofuran, furan and specific interaction