Bulletin of Pure & Applied Sciences- Chemistry
  • Year: 2019
  • Volume: 38c
  • Issue: 1

Volumetric and viscometric studies of copper soap urea complex derived from various vegetable oils in methanol-benzene mixture.

  • Author:
  • Arun Kumar Sharma1,, Meenakshi Saxena2, Rashmi Sharma3
  • Total Page Count: 12
  • Published Online: Jan 1, 2019
  • Page Number: 1 to 12

1department of Chemistry, Govt. P.G. College, Jhalawar-326001, Rajasthan, India

2Department of Chemistry, S.D. Govt. College, Beawar-305901, Rajasthan, India

3Department of Chemistry, S.P.C. Govt. College, Ajmer-305001, Rajasthan, India

*Corresponding Author Arun Kumar Sharma, department of Chemistry, Govt. P.G. College, Jhalawar-326001, Rajasthan, India. E-mail: sharmaarun423@gmail.com

Abstract

The density and viscosity of Cu (II) soap urea complex derived from four edible oils (mustard, groundnut, sesame, soyabean) in non-aqueous solvents of varying composition has been determined at constant temperature. The results were used to determine the critical micelle concentration (CMC), soap-solvent interactions and the effect of chain length of the soap urea complex molecule on various parameters. The CMC values in higher volume % of methanol are higher those in higher volume % of benzene, with regards to chain length of the soap urea complex CMC value follow the order: CSoU>CSeU> CGU > CMU The conclusions with regard to soap-urea complex and soap-solvent interaction have been discussed in terms of well-known Masson's and Jones-Dole equations. This vital information plays an important role in various industrial and biological applications.

Keywords

Cu(II) soap urea complex, Edible oils, Soap-solvent interaction, CMC, Density and viscosity