1department of Chemistry, Vijayanagara Sri Krishnadevaraya University, Jnana Sagara Campus, Ballari, Karnataka-583105, India
2PG Department of Chemistry, Basaveshwara Science College, Bagalkote, Karnataka, India.
3Assistant Professor, Department of Chemistry/Industrial Chemistry, Vijayanagara Sri Krishnadevaraya university, Jnanasagara campus, Cantonment, Bellary, Karnataka, 583105, India
*Corresponding Author Dr. Amshumali M.K., Assistant Professor, Department of Chemistry/Industrial Chemistry, Vijayanagara Sri Krishnadevaraya university, Jnanasagara campus, Cantonment, Bellary, Karnataka, 583105, India E-mail: amshumali.m@gmail.com
A synthesis of mono nuclear bis indacene mono metal compound of type [L-M-L] where (L is 2,6-diethyl-4,8-dimethyl-1,5-dihydro-s-indacene, M=Pd. Pd-bis (ƞ5-2,6-diethyl-4,8-dimethyl-1,5-dihydro-s-indaceneide) [Pd (Ic'H)2], and the oligomeric form of this compound is successfully prepared. The prepared compound is of the type [L-M-L-M-L-M-L] where M= Pd and L =-2,6-diethyl-4,8-dimethyl-1,5-dihydro-s-indaceneide)}] [Ic'Pd(μ-Ic’) Pd (g-Ic’)Pdlc’] the reaction yields a almost quantitative yield. The synthesized compounds were characterized by NMR (1H and 13C), and elemental analysis. The spectroscopic data reveals the formation Multidecker compound. This oligomer is further subjected to catalytic property study
Palladium organometallics, S-indacene, Multidecker, Sandwich