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Surface segregation is an important to monitor many properties of liquid alloys. The statistical approach, which derived from the concept of a layered structure near the interface, is widely used. The grand partition functions set up for the surface layer and that of the bulk provides a relation between surface and bulk compositions. The variation of the surface composition in AlGa and AIGe liquid alloys suggests that the degree of segregation is more in AlGa system than that of AIGe system.
Surface segregation, AlGa and AIGe liquid alloys, AlGa system, AIGe system, Grand partition, Statical on odd surface tension, Exess energy, Coordination number