1Department of Chemistry, Handique Girls’ College, Guwahati, India
2Karimganj College, Karimganj, India
*Corresponding author: bapan.chem@gmail.com
Online published on 20 June, 2013.
Olive-green oxo-bridged Co (III) complex tetrakis[(μ3-oxo) (μ-4-chlorobenzoato-O) (4-methylpyridine) cobalt(III)] having the formula Co4 (μ3-O)4 (μ-O2C.C6H4-4-Cl)4 (4-Me-py)4 is synthesized by modification of a reported synthetic method. The synthetic method involves hydrogen peroxide oxidation of a mixture of Co (II), 4-chlorobenzoic acid and 4-methylpyridine in a 1:2:1 molar ratio in methanol. Spectral studies suggest the presence of a distorted cubane-like core of [Co3 (μ3 -O)4]3+ in the complex. The complex is found to exhibit inhibitory effect on Escherichia coli in a dose dependent manner.
Cubane cluster, antibacterial, E. Coli.