International Journal of Applied Chemistry

  • Year: 2006
  • Volume: 2
  • Issue: 3

A Novel Synthesis of New Platinum(II) Complexes With N-(Substituted Aryl or Benzyl)-Г-Mercaptobutyramides by Using Phase Transfer Catalysis

  • Author:
  • Ja'afar K. Jawad1,, Jasim M. Al-Sabawi2
  • Total Page Count: 11
  • DOI:
  • Page Number: 209 to 219

1Chemistry Department, College of Science, Sultan Qaboos University, P.O. Box 36, Al-khod 123, Muscat, Sultanate of Oman.

2Department of Chemistry, College of Education, Salahaddin University, Erbil, Iraq.

Abstract

The synthesis of platinum phosphine complexes containing N-(substituted aryl or benzyl)-γ- mercaptobutyramides by using phase transfer catalysis are reported. Complexes of the form [{4X-C6H4NHCO(CH2)3S}2Pt(PMe2Ph)2], where X = OCH3, CH3, Cl, benzyl, have been synthesized by the reaction of cis-dichlorobis (dimethylphenylphosphine) platinum(II) with the corresponding N-(substituted aryl or benzyl)-γ-mercaptobutyramide in a two phase system of water and chloroform in the presence of benzyl triphenyl phosphonium chloride. The complexes were characterized by elemental analysis, i.r, and 1H, and 13C NMR spectroscopy.