International Journal of Applied Chemistry
  • Year: 2010
  • Volume: 6
  • Issue: 2

Photochemical Reactions of [M(CO)6] (M=Cr, Mo & W) with di & tri-dentate Schiff Bases

  • Author:
  • Ayodhya Singh1, Munesh Kumar2, Manish Kaushik2, Seema Singh3, Ruchi Kaushik1, Anjali Singh1
  • Total Page Count: 9
  • Page Number: 215 to 223

1Department of Chemistry, M.M.H. College, Ghaziabad, U.P., India, 201001.

2Department of Chemsitry, D.P.B.S. College, Anoopshahr, Bulandshahr, U.P., India, 203001.

3Department of Chemsitry, Kishan P.G. College, Bahraich, U.P., India, 271801.

Abstract

Some new noble Schiff bases viz., 2,4-dibromo-6-{[cyclohexyl(methyl)amino] methyl}-N-(−4-methoxyphenyl methylidene)aniline (BROM-ANIS), 2,4-dibromo-6-{[cyclohexyl(methyl)amino]methyl}-N-(−2,4-dimethylphenyl methylidene)aniline (BROM-DMB) & 2,4-dibromo-6-{[cyclohexyl(methyl)amino]methyl}-N-(−2-methylphenyl methylidene)aniline{[cyclohexyl(methyl)amino]methyl}-N-(−3-methoxy-2-hydroxyphenyl methylidene)aniline (BROM-o-VANI) react with G-6 metal hexacarbonyl in benzene to give trisubstituted derivatives. The synthesized complexes exhibit variable degree of antibacterial activity. The complexes were characterized on the basis of physical properties, elemental and infrared analyses.

Keywords

Schiff Bases, G-6 Metal Carbonyl, Antibacterial activity