Invertis Journal of Renewable Energy
  • Year: 2013
  • Volume: 3
  • Issue: 2

Potential Specific Capacitance in Layered Nickel Ferrite Electrochemical Supercapacitors

  • Author:
  • B.J. Lokhande1,, R.C. Ambare1, R.S. Mane2, S.R. Bharadwaj3
  • Total Page Count: 10
  • Page Number: 79 to 88

1School of Physical Sciences, Solapur University, Solapur-413 255

2Center for Nanomaterials and Energy Devices, School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded-431 606

3Chemistry Division, Bhabha Atomic Research Center, Trombay, Mumbai-400 085

*E-mail: bjlokhande@yahoo.com

Online published on 10 August, 2015.

Abstract

Nickel ferrite electrodes for electrochemical supercapacitors were made from a successive ionic layer adsorption and reaction (SILAR) chemical method. Their structural elucidation and morphological evolution studies were made and further investigated in electrochemical cyclic-voltammetry characteristic measurement. Face-centered cubic crystal structure of nickel ferrites composed of several irregular islands is confirmed. Brief flow chart is discussed for clear in-depth understanding of the formation nickel ferrite. Due to a significant reversible pseudocapacitive contribution nickel ferrite electrochemical supercapacitor contributes 555.5 F/g specific capacitance at 2 mV/s. Electrochemical impedance analysis measurement, along with an equivalent circuit details, is also provide for understanding the charge transport kinetics across various interfaces.

Keywords

SILAR, nickel ferrite, electrochemical supercapacitor, cyclic-voltammetry, impedance analysis