Journal of the Indian Society of Soil Science
SCOPUS
  • Year: 1985
  • Volume: 33
  • Issue: 3

A Thermodynamic Approach to the Adsorption of Phosphamidon with H- and Na-Montmorillonites

  • Author:
  • O.P. Bansal, Namita Singh
  • Total Page Count: 7
  • Page Number: 513 to 519

Chemical Laboratories, D.S. College, Aligarh, Uttar Pradesh, 202001

*Present address: Chemistry Department, T.R.K. Mahavidyalaya, Aligarh, U.P., 202001

Abstract

Adsorption of phosphamidon (dimecron) on montmorillonites was investigated in terms of isotherms, Langmuir equation and thermodynamic parameters-Langmuir analysis pointed to two regions with two distinct mechanisms of dimecron adsorption on the clay mineral. Langmuir constants reflected the magnitude and affinity of adsorption as influenced by temperature, concentration and exchangeable cations. Values of thermodynamic equilibrium constont, Gibb's free energy, enthalpy and entropy supported the inferences drawn. A mechanism for adsorption of the pesticide on montmorillonites is also proposed.

Keywords

Adsorption of pesticide, mont-morillonite, adsorption isotherm, phosphamidon, thermodynamics of adsorption