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This work constitutes a part of the Ph.D thesis of CD. Contribution No. 514 from Division of Agricultural Chemicals.
Nimbin (1), 4-epinimbin (2) and 6-desacetylnimbin (3) were converted into nimbolide (6) and two novel pentanortriterpenoidal congeners viz. desacctylnitnbinene, (8) and nimbinene (9). The two dimensional 1H HOMCOR spectrum of 1, mass spectra of 2 and 4-epinimbic acid (5), 1H and 13C nmr spectral data of 6 and pyronimbic acid (7) are also presented.