1Assistant Professor, Department Chemistry, AMET University, Kanathur, Chennai, 603 112, India
2Assistant Professor, Department of Chemistry, Madras University
*Corresponding Author E-mail: nitrosiva@yahoo.co.in
Online published on 16 May, 2018.
For the first time Baylis-Hillman adducts derived from nitro olefins have been conveniently transformed into a novel class of building blocks, (E)-(3-chloro-2-nitroprop-1-enyl)benzene. The large second order optical nonlinearities, short transparency cut-off wavelength and stable physiochemical performance, which are needed in the realization of most of the recent electronic applications, are also considered in the present study.
Baylis-Hillman reaction, nitro olefin, (E)-2-nitro-3-phenylprop-2-en-1-ol, TiCl4, THF and (E)(3-chloro-2-nitroprop-1-enyl)benzene
