Research Journal of Science and Technology

  • Year: 2016
  • Volume: 8
  • Issue: 4

Complexation Behavior of 1-Phenyl-2,3-dimethyl-4-(benzylamino) pyrazol-5-one Schiff Base Ligand with Manganese ion

Department of Chemistry, Michael Okpara University of Agriculture, Umudike, Nigeria

*Corresponding Author E-mail: ifeanyiotuokere@gmail.com

Online published on 30 December, 2016.

Abstract

Complexation behaviour of the Schiff base ligand, 1-phenyl-2,3-dimethyl-4-(benzylamino)pyrazole-5-one with manganese metal ion has been studied. The Schiff base ligand, 1-phenyl-2,3-dimethyl-4-(benzylamino)pyrazol-5-one was synthesized by the condensation reaction of 4-aminoantipyrine and benzaldehyde. The ligand and complex were characterized based on their colour, melting point, solubility, infrared and mass spectral analyses. Spectroscopic analyses suggested the involvement of C=N, C=O and chloride ions in chelation. A tetrahedral geometry was suggested for the manganese complex.

Keywords

1-phenyl-2, 3-dimethyl-4-(benzylamino)pyrazol-5-one, manganese, mass spectra, infrared, Schiff base