Annals of Plant Protection Sciences

  • Year: 2009
  • Volume: 17
  • Issue: 2

Synthesis and Nematicidal Activity of 2-Tridecanone and its Oxime Esters against Meloidogyne incognita

  • Author:
  • Rupak Paul, Suresh Walia, Achintya Mondal, Jitendra Kumar, Pankaj 1
  • Total Page Count: 3
  • DOI:
  • Page Number: 453 to 455

1Division of Nematology, I.A.R.I., New Delhi, 110 012, India.

Division of Agril. Chemicals, I.A.R.I., New Delhi, 110 012, India.

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Abstract

2-Tridecanone, 2-tridecanone oxime and its ten oxime esters were synthesized and evaluated for their nematicidal activity against Meloidogyne incognita. 2-Tridecanone was reacted with hydroxylamine hydrochloride to obtain 2-Tridecanone oxime. This on reaction with different acid chlorides yielded corresponding oxime esters. Compounds exhibiting more than 75% nematode mortality at 500 μg/ml dose were further evaluated at lower concentrations. 2-Tridecanone oxime N-O-nonanoate with LC50 of 73.16 μg/ml was identified as the most active followed by octanoyl ester (LC50 of 84.22 μ/ml). Valeryl and isovaleryl esters with respective LC50 of 150.42 and 125.65 μg/ml were moderately active. The activity of the most active compound was, however, less than the commercial nematicide triazophos (LC50 22.35 μg/ml).

Keywords

Meloidogyne incognita, 2-Tridecanone, 2-tridecanone oxime